Choice of dynamics for spin-crossover systems
نویسندگان
چکیده
Nikolay Klinduhov,1 Dmitry Chernyshov,2 and Kamel Boukheddaden3 1St.-Petersburg State University, 199034 St. Petersburg, Russia 2Swiss-Norwegian Beam Lines at ESRF, 6 rue Jules Horowitz, BP 220, 38043 Grenoble, France 3Groupe d’Etudes de la Matière Condensée, UMR-CNRS 8635, Université de Versailles St-Quentin, 45 Av. des Etats Unis, 78035 Versailles, France Received 25 November 2009; revised manuscript received 20 January 2010; published 8 March 2010
منابع مشابه
Comparison of structural dynamics and coherence of d–d and MLCT light-induced spin state trapping† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6sc05624e Click here for additional data file.
Light-induced excited spin state trapping (LIESST) in Fe spin-crossover systems is a process that involves the switching of molecules from low (LS, S 1⁄4 0) to high spin (HS, S 1⁄4 2) states. The direct LS-to-HS conversion is forbidden by selection rules, and LIESST involves intermediate states such as MLCT or T. The intersystem crossing sequence results in an HS state, structurally trapped by ...
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